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Metal Promoted Selectivity in Organic Synthesis

Released on 2012-09-24 by A. Noels
Metal Promoted Selectivity in Organic Synthesis

Author: A. Noels

Publisher: Springer

ISBN: 9401055084

Category: Science

Page: 373

View: 274

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The demand for selective organic reactions is growing more acute everyday. Indeed, greater product selectivity has an important impact on energy and resource utilization, in terms of reduced process energy requirements for product separation and purification, in terms of low-value by-products, and in terms of environmental acceptance and compatibility. Moreover, more and more chemicals, especially pharmaceuticals, have to be sold in an optically active form. The search for selectivity constitutes a tremendous challenge for the chemists. In the last two decades, homogeneous transition metal based catalysis has emerged as one of the most promising tools for obtaining selectivity. In connection with developments in this area, this book contains updated and expanded versions of most of the lectures presented at a Cornett course held in Trieste (Italy) in 1989 and sponsored by the European Community. A primary aim is to cultivate a deeper understanding of the parameters that govern the selectivities and stimulate a wider utilization of transition metal based catalysis in organic synthesis. All aspects of selectivity, chemo-, regio-, stereo- and enantioselectivity are considered and illustrated by applications in various fields or organic synthesis. The impact of catalysis in oxydation, reduction, carbonylation reactions, carbene chemistry, in Ni and Pd promoted dimerizations, oligomerizations as well as fonctionalisations is stressed, quite often with special emphasis laid on reaction mechanisms. In this aspect, the last chapter examplifies the interest of high pressure NMR and IR when investigating the nature of reaction intermediates in homogeneous reactions.

Metal Promoted Selectivity in Organic Synthesis
Language: en
Pages: 373

Metal Promoted Selectivity in Organic Synthesis

Authors: A. Noels, M. Graziani, A.J Hubert
Categories: Science
Type: BOOK - Published: 2012-09-24 - Publisher: Springer

The demand for selective organic reactions is growing more acute everyday. Indeed, greater product selectivity has an important impact on energy and resource utilization, in terms of reduced process energy requirements for product separation and purification, in terms of low-value by-products, and in terms of environmental acceptance and compatibility. Moreover,
Metal Promoted Selectivity in Organic Synthesis
Language: en
Pages: 373

Metal Promoted Selectivity in Organic Synthesis

Authors: A. Noels, M. Graziani, A.J Hubert
Categories: Science
Type: BOOK - Published: 2012-12-06 - Publisher: Springer Science & Business Media

The demand for selective organic reactions is growing more acute everyday. Indeed, greater product selectivity has an important impact on energy and resource utilization, in terms of reduced process energy requirements for product separation and purification, in terms of low-value by-products, and in terms of environmental acceptance and compatibility. Moreover,
Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds
Language: en
Pages: 468

Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds

Authors: K. Kalyanasundaram, M. Grätzel
Categories: Science
Type: BOOK - Published: 2013-06-29 - Publisher: Springer Science & Business Media

Photosensitization and photocatalysis refer to processes by which permanent chemical transformations are induced on substrates (organic/inorganic) by radiation to which the substrates themselves are transparent. Such transformations can be highly specific, very efficient, and occur under mild conditions. Herein lies the power of photochemical methods for possible applications in the
Advances in Catalytic Activation of Dioxygen by Metal Complexes
Language: en
Pages: 338

Advances in Catalytic Activation of Dioxygen by Metal Complexes

Authors: László I. Simándi
Categories: Science
Type: BOOK - Published: 2006-04-11 - Publisher: Springer Science & Business Media

The subject of dioxygen activation and homogeneous catalytic oxidation by metal complexes has been in the focus of attention over the last 20 years. The widespread interest is illustrated by its recurring presence among the sessions and subject areas of important international conferences on various aspects of bioinorganic and coordination
Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes
Language: en
Pages: 556

Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes

Authors: A.E. Shilov, Georgiy B. Shul'pin
Categories: Science
Type: BOOK - Published: 2001-11-30 - Publisher: Springer Science & Business Media

hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive

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